MECHANICS OF Low TEMPERATURE CRYSTALLIZATION AND RELATED CONSI­ DERATIONS

Authors

  • Nayeem uddina House No.R-14119, Asif Nagar Dastagir. Karachi-75950 , Pakistan
  • S Naeem Mahmood PCSJR Laboratories Complex Karachi, Off University Road,Karachi- 75280, Pakistan
  • Farzana Azmat PCSJR Laboratories Complex Karachi, Off University Road,Karachi- 75280, Pakistan

Keywords:

Supersaturation and spontaneous crystallization, Mechanics oflow temperature crystallization , Hydrodynamic/thermodynamics of batch crystallizer.

Abstract

Miers theory, although elucidated satisfactorily the phenomenon of supersaturation and consequent crystallization, nevertheless , failed to explain mechanics of POLTEC (processi of low temperature crystallization) in  a  batch  crystal­ lizer; which has been evolved based on observations made during earlier investigations /logic. It is proposed that because  of cooling, the layer in contact with the vessel 's wall gets supersaturated and is dispersed in solution and spontaneous adiabatic crystallization occurs in each element of dispersed phase . Subsequent to sprouting of salt from each globule, mixing of the liquid residuals causes smooth cooling of solution. Miers idea of required degree of supersaturation , its mechanics and that of POLTEC in context with fluid dynamics/hydrodynamic of batch  crystallizer  (stirred tank  vessel), has been found instrumental in explaining reasons lying behind the pattern of changes in overall heat transfer coefficient  and recovery  with  agitation  observed earlier.

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Published

2002-08-26

How to Cite

uddina, N., Mahmood, S. N., & Azmat, F. (2002). MECHANICS OF Low TEMPERATURE CRYSTALLIZATION AND RELATED CONSI­ DERATIONS. Biological Sciences - PJSIR, 45(4), 237–242. Retrieved from https://v2.pjsir.org/index.php/biological-sciences/article/view/1797

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